cis-Dichloro(di-n-butyl sulfide)(tri-n-butylphosphine)platinum(II)
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چکیده
منابع مشابه
(N-Butyl-N-phenyldithiocarbamato-κS)triphenyltin(IV)
The title compound, [Sn(C(6)H(5))(3)(C(11)H(14)NS(2))], features a tetra-hedrally coordinated Sn atom, as the dithio-carbamate ligand coordinates in a monodentate fashion. Due to the proximity of the non-coordinating thione S atom, distortions from ideal tetra-hedral geometry about the metal atom are evident with the widest C-Sn-S angle being 117.26 (5)°. In the crystal, mol-ecules are linked b...
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The P atom in the title mol-ecule, C(10)H(23)ClN(3)O(2)P, has a distorted tetra-hedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N-H groups, the P-N bond of 1.703 (2) Å is longer and the O-P-N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH(3))(3) units [P-N = 1.632 (2) and 1.624 (2) Å; O-P-N = 116.80 (8) and 115.32 ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section C Crystal Structure Communications
سال: 1993
ISSN: 0108-2701
DOI: 10.1107/s0108270192010266